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Skim the Cream II


An Article by George J. Reclos, Takis Tsamis & Andreas Iliopoulos
THIS ARTICLE APPEARED IN THE MARCH 2002 ISSUE OF FAMA

Effectiveness

Protein skimmers are considered the most effective chemical filtering devices, because they remove most of the organic compounds from the water by physical means (the only media that protein skimmers use are water and air), before they begin to break down into toxic compounds. So they give a helping hand to biological filters. Additionally, some bacteria and phytoplanktonic organisms are mechanically trapped in the foam and are removed alongside the organic matter. The adequate skimming, which removes all these organic nutrients, is the most sufficient way to control the growth of Cyanobacteria as well. It is not wise to use algaecides and antibiotics (erythromycin for instance) to control algae and Cyanobacteria, as an alternative to using a skimmer. Algae and Cyanobacteria will be killed, but they can return if there are enough nutrients in the environment. Therefore, it is preferable to work at the basis of the problem: elimination of excess organic matter.

Factors that dictate the efficiency of a protein skimmer are bubble size, airflow rate, and the active contact time of the bubbles in the skimmer. The desired bubble size is between 0.5 and 1.0 mm. This maximizes the surface area of the bubbles, without considerably lowering their buoyancy. Air flow rate dictates the relative ratio of water to air bubbles in the protein skimmer. The recommended airflow rate for protein foam skimmers is around 1.8 cm/sec per cm2 of cross-sectional area of the main cylinder of the protein skimmer. Having the correct flow rate will increase the skimmer's efficiency by creating good foam without compromising the active surface area of the bubbles. The active contact time of the bubbles is generally controlled by two factors - the height of the protein skimmer's main cylinder, and the flow rate of the water through the skimmer. There is no specific "golden" value for these since they are a strong function of the particular characteristics of each protein skimmer and aquarium setup.

Size - Installation

The size of a skimming device is, of course, related to the size of the tank we want to install it on. Generally, we can say that a 120 cm tall skimmer, with a diameter of its contact column of about 15 cm and a water flow rate of about 1.200 liters per hour can be used with a 600 liter aquarium. A skimmer should process at least the equivalent of one tank full of air and one tank full of water per hour. For most tanks, the water rate is easy. The air rate, however, is not. Most counter current (explained below) skimmers are under-supplied with air. If you have a sealed skimmer where the air can only exit from one fitting, it’s easy to measure the flow rate. Simply take a large plastic bag (something in the 2 gallon size works well), empty it, and place it over the air exhaust port. Time how long it takes to fill and do the math.

Three basic styles of skimmers exist: counter current air driven, venturi driven, and down-draft (see diagrams). All styles work fine, all have tradeoffs. All require some tuning. Expect to spend some time over the first month or so learning how to keep your skimmer tuned.

3. Typical co-current flow protein skimmer. Water and Air move to the same direction.

The place we shall install a skimmer is not so critical. We can place it inside the tank (internal skimmer), or outside it (hung or put in the sump). If it is the right skimmer for the tank and is the right size, it will produce foam either way. If it is placed in the sump, then it must be placed on the compartment that the water enters the sump. We recommend installing the skimmer before the sump, and, more specifically before the chemical and after the mechanical media. The reason for this is that many (visible or not) particles of wastes will be removed during mechanical filtration before entering the skimmer; therefore the chemical filtration compartment (usually activated carbon) will have less of a load to handle, prolonging its usefulness. The outlet of the skimmer can supply the biological media with skimmed water, after that. It is better when the water entering the skimmer is collected from the top of the water column of our tank and even better if it is collected from the drilled overflow of our tank. Make sure you have a very good design with valves and watertight piping, and take extra care with the water level and flow (see diagrams).

4. Environmental Tower Skimmer. Down-Draft Skimmer design.

For better results

·If you want effective skimming you’ll have to acquire the right size of skimmer, and make sure that flow is at least two times your tank volume per hour.

·Also, it must produce very fine bubbles (sizes between 0,5 mm and 0,8 mm are preferred) and a contact time that is as long as possible. The finer the bubbles are, the more surface is provided, and more time is needed for the bubbles to rise (more contact time). The taller the contact column, the longer the contact time.

·When we buy a skimmer, we have to check thoroughly if we can easily disassemble it completely.

·Check the collection cup and the “neck” (foam riser cylinder). They must be easily removable to allow for frequent service. The neck has to be long enough, so that the collected foam will dry out and be properly gathered.

·Check tubes, plumbing, inlets and outlets. The inlets and outlets have to have sufficient lumen for the quantities of water they administer.

·Take a good look at every valve on the system. Skimmers equipped with gate valves are easier to be adjusted with very fine controls (rather than the ones with ball bulbs). Ball bulbs are fine when used as gateways (just to open or close a system), but they are a bit inadequate for making fine adjustments.

·When you have to deal with an air – driven skimmer with a long contact tube, be sure that the air pump that supports it has enough power to pump enough quantity of air into it.

·Use more air stones. You should at least double the number of air stones recommended by the manufacturer. Remember that it is impossible to over-skim a tank. Wooden blocks make very fine bubbles. Skimmers with a diameter more than 10 cm work better with two wooden blocks, at least. First turn on the air pump, and then put the air stone into the water. It is harder for an air pump to push the water through a presoaked air stone (it is even harder with dense wooden blocks).

·Venturi systems do not need frequent replacement, but they do need some searching. Choose the ones with an installed adjust valve to get proper abundance of properly sized bubbles. The ones with a water pump installed (which powers the Venturi) fill the skimmer with a dense body of air bubbles (they are sold under the name “Venturi skimmers”). The pumps that are installed on such skimmers are equipped with needle wheels (impellers with many sharp flaps) for more efficient water – air mixture.

·Air stones and the air pump to supply them present a "what came first the chicken or the egg?" dilemma. Sure, you'd like to maximize your air volume while minimizing bubble size; but they're mutually exclusive goals. The best you can do is to have the most airflow you can with ideal, consistent bubble size (@ 1/2 millimeter). Glass and wood air stones work great when new/clean. Keep your eye on them and have at least two sets, one in use, and the other for cleaning/air-drying to extend their functional/useful life.  

5. A co-current protein skimmer. Due to its short reaction chamber, the contact time is minimal. This is the least effective of all protein skimmer designs and is mainly aiming at small tanks. Models with longer reaction chambers are available but require much more powerful air pumps.

6. Hang-on skimmer design

What to care for

Skimmers are very sensitive to changes occurring within them. Dust, insecticide or aromatic sprays and paint vapors affect their function. These substances decrease the foam production. Human body fat is also a factor that will suddenly decrease the foam produced by skimmers. Feeding also decreases foam production temporarily. This happens because oily or fatty substances, when introduced into the system, lower the tension of the water surface. So it is not strange to observe a decrease in the produced foam for several hours after feeding our fish or putting our hands in the tank water. 

The operation of skimmers is also affected by its mode of operation. Temperature, pH, water and air flow rates, dimensions of the contact column, surface tension, specific gravity, as well as other factors such as the properties of the bubbles (size, abundance and distribution of air bubbles, as well as the method used to produce them) affect the performance of the skimmer.

We have to clean the device and empty the collection cup regularly. Both the dry (standard) and the wet (protein) foam are poisonous because of their high concentration in toxic compounds. Make sure that none of it is dropped back into the tank, either because of a mistake or due to an improperly designed construction. Some commercial skimmers are equipped with an overflow on the collection cup. Through this overflow, skimmed protein foam is drawn away from the collection cup. You can drill a hole (12/16 is enough lumen) if there is no overflow in your skimmer and with a tube you can dispose the wet foam into a container or directly into your domestic drainage system.

Lots of turbulence at the top of the contact column prevents the correct separation of the dry foam and skimmed water, thus decreasing its performance. The pH affects foam formation, too. As pH changes throughout the day, the skimmer operates with a varying efficiency. The higher the pH, the stronger the bonds of the organic molecules to the bubbles’ surface.

Because of the differences in the structure of various proteins, some of them are skimmed easier than others since the pH also affects their ionization (the further away from their isoelectric point the more ionized they become), which is directly linked to their degree of electrostatic attraction.  

Specific gravity also affects skimming, because dissolved salts increase the stability of the bubbles (greater water viscosity).

Last, but not least, when temperature increases, surface tension is decreased. The higher the temperature the more readily foam breaks, and its formation is dry and stable.

7. Stand-alone skimmer design.

Disadvantages

Protein skimmers, in general, remove trace elements from the water, so we have to replenish them. This is accomplished with regular water changes, which introduces them back into the tank with the introduction of fresh tap water.

The air – driven protein skimmers have some disadvantages when compared to the motor – driven ones. Their main problem is because they are not able to supply a constant and stable quality of air bubbles.

8. An example of a Sump-mounted Venturi protein skimmer.

continued in next page

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